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Veritasium
The Perfect Battery Material Is Dangerous
The Perfect Battery Material Is Dangerous
Veritasium
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34:42 · Aug 7, 2025
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This
is
what
the
inside
of
a
lithium-ion
battery
looks
like.
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0:00
- This is what the inside of a lithium-ion battery looks like.
0:03
It's not exactly high tech, just two meters of foil coated in black paste,
0:08
all packed into this tiny 45 gram cylinder.
0:12
But these are some of the best batteries we have.
0:15
They power everything from laptops and electric vehicles to orbiting satellites.
0:20
Yet when a battery fails,
0:21
all that energy can get released in the wrong way. - Oh my God.
0:26
- The latest incident involving a lithium-ion battery. -
0:30
So how did something
0:31
so rudimentary looking end up in almost every electronic device on the planet?
0:37
And why don't we have anything better?
0:39
In the early 1980s,
0:41
most rechargeable batteries were stuck at just 40 to 60 watt hours per kilogram,
0:46
meaning you would need a kilogram of battery to power a 40 watt light
0:50
bulb for just an hour.
0:52
As a result, when the first commercial mobile phone launched in 1983,
0:56
it was pretty unimpressive.
0:58
It took 10 hours to charge for just 30 minutes of talk time.
1:02
Laptops, cameras, even medical devices all suffered from the same bulky batteries.
1:07
Everyone from electronics giants to oil companies were trying to make a better battery,
1:11
because they knew that even just doubling the energy density could unlock a new
1:16
era of portable electronics
1:17
and power the digital revolution.
1:19
But what no one realized is that someone had already found the solution.
1:25
In 1972, a 32-year-old British chemist named Stanley Whittingham was studying how different materials
1:31
store energy at Exxon's research lab in New Jersey.
1:35
Yes, that Exxon, the multinational oil giant,
1:38
then the largest oil company in the world.
1:41
They were researching batteries.
1:45
The next year, war broke out between Egypt, Syria, and Israel.
1:49
When the US backed Israel, Arab oil producers cut off oil exports in retaliation.
1:54
And on December 22nd,
1:56
the price of crude oil more than doubled from $5.12 a barrel to 11.65.
2:02
In response, President Nixon created policies to try to keep oil prices down,
2:06
but they backfired and the shortage only got worse.
2:09
Americans were left queuing for hours at gas stations
2:13
as the government introduced a rationing program.
2:15
It got so bad
2:16
that they even dropped the national speed limit to 55 miles per hour just
2:20
to cut consumption.
2:23
At Exxon, executives were worried that supplies would run out entirely,
2:28
so they started looking seriously at alternatives, like electricity.
2:33
This wasn't a new idea.
2:34
In fact, in 1900 when cars were first taking off,
2:37
the top selling car was electric, ahead of steam and gas powered cars.
2:42
But the problem with these electric cars was their batteries.
2:45
They weighed 360 kilograms, around 40% of the car's weight,
2:50
but they could only take you around 60 kilometers.
2:53
And the energy density wasn't just low, it also degraded over time.
2:57
Every time you recharged, it got worse.
2:59
After fewer than 500 charges, your range would've dropped to about 40 kilometers.
3:05
So by 1924, gas powered cars outnumbered electric 10,000 to one.
3:11
But now that the oil supplies were running out,
3:13
it seemed to Exxon
3:14
that there was no other solution than to bring back the electric car,
3:17
and to do that, they needed a battery with a much higher energy density.
3:21
So suddenly, Whittingham's side project became a top priority.
3:25
Exxon poured in resources, giving him free rein to, in his words,
3:30
"Do pretty much what I wanted, as long as it did not involve petroleum."
3:34
The very first battery dates back to a curious incident in the 1780s
3:39
when Italian scientist Luigi Galvani was dissecting a frog to study its anatomy.
3:45
He anchored one side of the frog on a brass hook
3:47
and went to cut it open with a steel scalpel.
3:50
But when he touched the scalpel to the frog's leg,
3:52
he noticed it suddenly twitched, as if it had come back to life.
3:57
Galvani believed he'd discovered a sort of animal electricity,
4:00
a living force produced by the tissue itself.
4:03
But Galvani's rival Alessandro Volta disagreed.
4:07
He thought it came from the metals themselves.
4:10
And you can see this with lots of different materials.
4:12
Veritasium producer Gregor set up a version of this experiment, minus the frog,
4:17
to test it out. - I have zinc, magnesium, and iron here.
4:21
I can take any of these metals,
4:23
stick them into one side of a lemon
4:26
and stick some copper on the other side.
4:29
If I hook these up to a volt meter,
4:30
I should be getting a voltage.
4:33
And we got around 0.8 volts.
4:35
Now, the reason this happens is
4:37
because some elements want to get rid of their electrons more than others.
4:40
So if you pair one
4:41
that really doesn't want its electrons with one
4:44
that really wants some,
4:46
well, then the electrons are gonna be traveling across. - Let's look at the zinc.
4:50
What's happening here is that zinc is losing its electrons.
4:54
The zinc ions enter the juice,
4:56
and the electrons are forced to go through the circuit to get to the
4:58
other side.
5:00
There, hydrogen ions in the lemon juice want those electrons,
5:03
so they receive them and turn into hydrogen gas.
5:07
You've got one side that gives up electrons, that's the anode,
5:10
and you've got one that receives them,
5:12
that's the cathode. - But why do you need the lemon at all?
5:15
If there's no flow of the positive ions through to the other side,
5:19
the electrons stop moving almost immediately.
5:22
This happens because all of the electrons now get bunched up in the copper,
5:26
making it extremely negatively charged,
5:28
and that is just gonna push away any more electrons from coming over to
5:31
the other side. - That's
5:33
because electrons can't travel through lemon juice.
5:35
Liquids like this don't have free electrons the way metals do,
5:38
so electrons stay in the wire.
5:41
They'll only leave the circuit at the copper side
5:43
if there's something in the juice,
5:44
like hydrogen ions ready to take them,
5:47
and if the reaction releases enough energy to make that transfer happen.
5:51
But positive ions in the juice can move.
5:53
They travel across to balance the charge, allowing the current to keep flowing.
5:57
A solution that carries charge this way by moving ions is called an electrolyte.
6:03
- But we could also do this with the other metals to get a
6:06
similar reaction,
6:07
and we can actually quantify how much each of these metals wants
6:11
or doesn't want electrons.
6:13
With zinc, we already got around 0.9 volts,
6:16
but if you try it with iron, for example, you get something lower,
6:19
0.5 or 0.6 volts.
6:22
Now, magnesium is tricky and it would be a bit higher,
6:24
but it oxidizes so quickly
6:26
that even if I scrape some of the oxide from the surface,
6:29
I'm still getting only around 0.7 volts.
6:34
The idea is that the larger the voltage on the volt meter,
6:37
the more energy each electron has to give as it passes through the circuit.
6:42
But there's also a limit to this.
6:44
See, this beaker is full of lemon juice from the lemons we used earlier,
6:48
and they're hooked up using spoons and these wires to a variable power source.
6:52
Now look what happens when I up the voltage.
6:56
You'll actually start to see bubbles forming on both spoons,
7:00
and that's water in the lemon juice actually being broken down into oxygen
7:04
and hydrogen gas.
7:06
This already starts happening at 1.23 volts,
7:09
and that sets a limit on how much voltage you can push through this
7:15
electrolyte. - Up until the early 1970s,
7:17
just about every commercial battery used a water-based electrolyte, and as a result,
7:22
none of these battery cells could push much beyond the 1.23 volt limit.
7:27
Now, the total energy a battery can store depends on how much energy each
7:31
charge has to give times how much charge can move,
7:34
that is the battery's voltage times its capacity.
7:38
So if you can't increase the voltage,
7:40
your only option is to make more battery, more cells or bigger cells,
7:44
but that won't increase the energy density.
7:48
And this is exactly the problem Whittingham was trying to solve.
7:52
He was searching for materials
7:53
that could store large amounts of energy in a compact space with light weight.
7:58
That led him to a class of compounds called transition metal dichalcogenides.
8:02
He zeroed in on one in particular, titanium disulfide.
8:06
Titanium in this compound has effectively lost four electrons, two to each sulfur atom,
8:12
meaning it sits at a plus four oxidation state.
8:15
That leaves it very electron hungry, exactly what you want in a battery cathode.
8:20
But titanium disulfide has a second key advantage,
8:24
this material is made of stacked layers held together by weak Van der Waals
8:27
forces.
8:28
This creates natural gaps between sheets of titanium
8:31
and sulfur atoms just wide enough to let certain ions slip between the layers,
8:35
a process known as intercalation.
8:38
Better still, the structure can expand and contract repeatedly without breaking down.
8:43
Now Whittingham just had to decide which ions to use.
8:48
He initially looked at potassium,
8:50
but it was just too reactive and far too dangerous to work with.
8:54
Oh, yeah!
8:57
(laughs) - He turned to this, a soft, silvery metal called lithium.
9:03
What makes lithium unique is not the fact
9:05
that it has one electron in its outer shell
9:08
that it wants to get rid of.
9:09
No, that it shares with the other elements in its group.
9:12
What sets it apart is how much energy you can get out of lithium
9:16
when it reacts in a battery.
9:18
See, when it loses that outer electron, it forms a tiny,
9:21
incredibly stable positive ion,
9:24
and so that reaction paired with the right cathode releases more energy per electron
9:30
than any other metal.
9:31
That's why it produces the highest voltage of any metal used in batteries.
9:36
And because it's so small with just three protons,
9:39
lithium is also the least dense metal,
9:41
at just 0.53 grams per cubic centimeter.
9:44
This combination of low density
9:46
and the tendency to give away its electron made lithium perfect for Whittingham's vision
9:51
of this high energy density battery.
9:53
But while lithium was easier to work with than potassium,
9:57
easier still didn't mean easy.
9:59
I mean, they only let me hold it in this glove box,
10:02
and matter of fact,
10:03
here's what happens to lithium
10:04
if you put it in a glass of water. (water bubbles) (tense music) Safe
10:11
to say,
10:11
you don't want this happening inside your battery. - So,
10:15
Whittingham had to switch out the water-based electrolyte for something else,
10:19
and that change unlocked the possibility of higher voltages.
10:24
He turned to a solution of lithium salt in an organic solvent,
10:28
and it worked, but it came with serious risks.
10:33
The solvent was volatile, the lithium salt was chemically unstable.
10:37
Together, they formed a mixture that could explode or release toxic fumes if mishandled.
10:42
Everything had to be done with extreme caution.
10:44
A stray spark or a trace of moisture could destroy the experiment
10:48
or start a fire.
10:49
But if you could get around the danger,
10:51
this new electrolyte was a huge perk.
10:54
It let lithium-ions shuttle between electrodes without breaking down the solvent
10:58
or the cell,
10:59
at least not until much higher voltages.
11:02
Whittingham had unlocked lithium's potential, and in the process,
11:05
he'd broken through the 1.23 volt ceiling.
11:08
His new chemistry delivered nearly double, a huge 2.4 volts per cell.
11:14
He now had a working prototype, a metallic lithium anode on one side,
11:18
a titanium disulfide cathode on the other, his new liquid electrolyte in between.
11:23
There was also a thin porous separator that kept the electrodes apart,
11:26
so they couldn't touch and short circuit.
11:29
Here's how it works.
11:30
When you close the circuit, lithium atoms at the anode give up their electrons.
11:34
Those electrons travel through the external circuit toward the cathode,
11:38
generating a current that powers whatever's connected.
11:40
At the same time, the lithium-ions are released into the electrolyte,
11:45
and then they pass through the porous separator and migrate toward the cathode.
11:49
The electrons arriving through the circuit are taken up by the titanium atoms
11:52
and the titanium disulfide.
11:54
The positive lithium-ions slide between the layers to balance out the negative charge of
11:59
the electrons,
12:00
and they become locked in place.
12:02
And this process is reversible.
12:04
When you apply a voltage to recharge,
12:06
the extra electrons are stripped from the titanium and pulled back to the anode.
12:10
The lithium-ions are forced out of the titanium disulfide layers into the electrolyte,
12:14
and they too migrate to the anode where metallic lithium reforms.
12:19
What Whittingham had created here was a rechargeable battery,
12:22
one that worked reliably cycle after cycle with incredible consistency.
12:28
I don't normally think about batteries this way,
12:30
but what they really are is tiny little contained chemical reactions.
12:35
And in a chemical reaction, if you could get a 60% yield,
12:39
that would be considered good.
12:41
But in a battery, especially one that you wanna recharge 1000 times,
12:45
you need that reaction to be say 99.9% efficient, because if it's not,
12:51
the capacity of that battery rapidly deteriorates.
12:54
If you have, say, a 95% yield,
12:56
then you'd lose a significant fraction of lithium-ions every cycle.
13:00
After just 50 cycles, you'd only have 8% of your original capacity left.
13:05
So that's pretty incredible that every single lithium-ion has to leave one electrode,
13:10
pass through the electrolyte,
13:11
and slot neatly into the layered crystal structure of titanium disulfide.
13:14
And then when you recharge it, they have to leave again cleanly without incident,
13:19
without getting stuck, make their way all the way back to the anode.
13:22
Amazingly, despite just being an early prototype, Whittingham's battery came close to that 99%.
13:30
In the winter of 1973,
13:32
Exxon's managers summoned Whittingham to the company's New York office.
13:37
Whittingham later said, "I went in there and explained it, five minutes,
13:41
10 minutes at the most, and within a week they said yes,
13:44
they wanted to invest in this."
13:47
They got to work at the Exxon laboratory, but it wasn't all smooth sailing.
13:51
Firefighters had to be called out repeatedly.
13:54
They were called so often,
13:55
they threatened to start charging the lab for the special chemicals needed to extinguish
13:59
the burning lithium. - The problem was the anode.
14:02
Whittingham's design used pure lithium, which worked brilliantly,
14:06
until it didn't. - We've made a special cell.
14:09
We've made a transparent battery. - That's so cool. - But they're very, very small,
14:13
so we have a microscope lens just to allow us to see it.
14:17
What you're seeing here is a piece of copper,
14:20
which we're gradually plating with lithium.
14:23
So this is analogous to the first generation lithium metal batteries,
14:27
which use lithium metal as the anode.
14:30
On this side, we have a piece of lithium.
14:32
As we charge the battery,
14:34
we're stripping the lithium from that electrode and we're plating it.
14:37
And actually what's happening right now is the ideal reaction where it's very slow.
14:42
We're getting a dense plate.
14:44
The challenge then becomes if we go too fast. - Oh,
14:49
that is huge! - Everything's fine until all of a sudden it's not fine.
14:55
So we want the lithium to plate evenly across everywhere, but instead,
14:59
it forms in that one location, and that is what is a lithium dendrite.
15:04
That lithium dendrite can grow.
15:06
The length scales of this is on the order of, you know, millimeters,
15:11
so that would've easily short circuited the battery. -
15:14
And that dendrite can just keep growing,
15:17
and eventually it's gonna poke through the separator and reach to the other side.
15:21
Now the electrons are gonna have a shortcut,
15:23
so instead of going through the circuit,
15:25
they race straight from the anode to the cathode using the dendrite,
15:29
and that sudden surge of electrons cause intense heating,
15:32
and that can trigger a chain reaction inside the battery, leading to a fire,
15:37
or even an explosion. - For all its promise, Whittingham's battery was just too dangerous,
15:44
and then the oil crisis ended.
15:47
Prices dropped and Exxon's urgency evaporated.
15:50
The company shut down its lithium battery program.
15:53
Whittingham published his design in 1976,
15:56
and Exxon licensed the patent to a few manufacturers,
15:59
but with no funding and no momentum,
16:01
the first lithium battery revolution died before it had a chance to take off.
16:06
Fortunately, a copy of Whittingham's paper made it across the Atlantic to Oxford University
16:10
in England,
16:11
where it caught the attention of John B.
16:13
Goodenough, an American physicist leading a solid state chemistry group.
16:18
As he read the paper, one thing stood out,
16:20
the cell voltage was being held back.
16:23
The material Whittingham chose for the cathode, titanium disulfide,
16:27
capped the cell at just 2.4 volts,
16:30
but Goodenough believed that with a better cathode material, he could do better.
16:35
He had previously worked with compounds called transition metal oxides.
16:39
They were more stable than sulfides,
16:41
and some he knew were extremely hungry for electrons, perfect for a cathode.
16:46
He tried one of these compounds in his battery,
16:48
and the voltage immediately spiked from 2.4 volts to four volts.
16:52
This jump was incredible.
16:54
But what was even more surprising was the fact
16:56
that this compound already had lithium in it.
16:59
The material was lithium cobalt oxide.
17:04
Lithium cobalt oxide is arranged
17:05
so that the cobalt
17:06
and oxygen atoms form tightly bonded layers,
17:09
with lithium-ions nestled in between.
17:12
This means that your supply of lithium-ions doesn't just have to come from the
17:15
dangerous lithium metal on the anode side,
17:18
it's already there prebuilt into the cathode.
17:21
So theoretically, you don't even need lithium metal at all.
17:24
You could assemble the cell in a discharged state with all your lithium-ions in
17:29
the cathode,
17:29
then when you connect it to a charger,
17:31
these ions will get expelled from the cathode crystal lattice and into the electrolyte.
17:35
At the same time,
17:36
nearby cobalt atoms will give up an electron to balance out the charge,
17:40
and those electrons then go through the wire to the anode to meet with
17:43
the ions.
17:44
If Goodenough could find an anode that would replace lithium metal,
17:48
the battery would become safe enough to leave the lab
17:50
and actually power real world devices.
17:53
Goodenough was so excited about the potential of his design
17:56
that he reached out to battery companies across the US,
17:59
the UK and Europe, but incredibly, no one was interested.
18:04
So he asked Oxford to file a patent, but they refused.
18:09
So he took it to a government lab near Oxford,
18:12
the Atomic Energy Research Establishment, and finally, they agreed to fund the patent,
18:17
but only if Goodenough signed away his financial rights.
18:22
Seeing no other option, he agreed, and the lab patented the invention in 1981.
18:27
Now, this should have been a gold mine,
18:30
but the lab didn't realize what they had.
18:32
And so for the second time,
18:34
the lithium battery revolution was boxed up and shelved.
18:38
This should have been a turning point for battery science,
18:40
but bureaucracy and inertia stalled progress.
18:44
Every field has its bottlenecks.
18:46
For batteries, it was slow moving institutions.
18:49
For developers today, it's slow moving code reviews.
18:52
And I can relate.
18:54
When we make these videos, especially the ones with simulations or complex animations,
18:58
it's rarely the ideas that slow us down, it is the reviews.
19:02
Developers face the same thing.
19:03
They're writing code faster than ever, thanks to tools like Copilot and Cursor.
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But code reviews, well, they're still manual and still slow.
19:12
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20:01
And now back to Goodenough's design, a breakthrough with nowhere to go, yet.
20:07
While Goodenough's battery design was gathering dust, 10,000 kilometers away in Japan,
20:12
a 34-year-old chemist named Akira Yoshino was trying to find a safer battery anode,
20:17
one that didn't require lithium metal.
20:19
Yoshino was actually looking at plastic.
20:22
Now, normally plastic is an insulator,
20:24
but the kind Yoshino was looking at is different.
20:28
It's called polyacetylene, and its carbon atoms are arranged in a repeating chain of
20:33
single and double bonds,
20:34
a structure that gives it unusual electronic properties.
20:38
If you tweak polyacetylene by adding or removing electrons,
20:41
electrons can actually move along this carbon chain.
20:44
So the plastic conducts electricity like a metal.
20:48
And that got Yoshino thinking, what if polyacetylene could work as a battery anode?
20:53
During charging, it could absorb lithium-ions and electrons, and then during discharge,
20:58
it would give up those electrons to the circuit, just like lithium metal does.
21:02
If it worked, it could eliminate the most dangerous part of the battery,
21:06
the metallic lithium.
21:08
But for months, Yoshino struggled.
21:10
Obviously, since he removed lithium metal from the anode,
21:12
he had to get lithium-ions from somewhere else
21:15
and he couldn't figure it out.
21:17
And then just as he was losing hope,
21:19
on the last workday of 1982 while cleaning out his office,
21:23
he stumbled upon a 1980 paper by John B.
21:25
Goodenough.
21:26
It described a cathode made of lithium cobalt oxide,
21:29
a cathode that already contained lithium.
21:33
This was the missing piece.
21:35
He sketched out the reaction between lithium cobalt oxide and his lithium free anode,
21:40
and then built a test cell using the two materials.
21:43
It worked safely and reliably, but Yoshino wasn't satisfied.
21:48
The material he used for the anode, the polyacetylene had an extremely low density.
21:53
I mean, it couldn't pack in enough lithium,
21:56
so the energy density of the battery was terrible.
21:59
Yoshino needed something more lightweight, compact, conductive, and crucially,
22:04
something that could reversibly accept
22:05
and release lithium-ions within its structure without breaking down.
22:09
He tested material after material, and every single one failed,
22:13
until a breakthrough came from within his own company.
22:16
Another team had developed a new form of carbon with a unique crystalline structure.
22:21
They called it vapor grown carbon fiber.
22:23
He got his hands on a sample, tried it in the lab,
22:26
and it worked.
22:29
To prove it, he placed a test cell containing metallic lithium into a safety
22:34
rig,
22:34
one that's designed to test explosives.
22:36
Then he dropped a heavy iron rod onto it.
22:40
It exploded violently.
22:42
Then he ran the same test again, but this time with his new design,
22:45
using carbon as the anode.
22:47
He charged the cell, placed it in the rig,
22:49
and dropped the rod but nothing happened.
22:53
The contrast was undeniable.
22:57
Later, Yoshino would say,
22:59
"That was the moment when the lithium-ion battery was born."
23:03
But his employer, Asahi Chemical, well, they weren't a battery company,
23:08
and they didn't know how to make batteries.
23:10
So in 1986, Asahi executive Isao Kuribayashi flew to Boston on a top secret
23:16
mission,
23:17
carrying three jars containing cathode, anode and electrolyte materials.
23:22
He handed them to a tiny firm called Battery Engineering,
23:25
working out of a converted truck garage,
23:27
and he asked them to turn the materials into cylindrical cells,
23:31
like the kind you might buy for a flashlight.
23:33
The team did just that, completely unaware of what they were handling.
23:38
It wasn't until 2020
23:39
that employees learned the truth
23:41
that they had helped assemble the world's first pre-production lithium-ion batteries.
23:43
Two weeks later, Kuribayashi returned to Japan with 200 finished perfectly functioning cells.
23:53
Even then, Asahi's leadership hesitated.
23:56
Kuribayashi refused to give up.
23:58
On the 21st of January, 1987,
24:00
he visited Sony and he took one of the prototype cells
24:03
and rolled it across the conference table to the Sony execs,
24:06
and at last, they saw its potential.
24:10
They reworked the design,
24:11
swapping out Yoshino's carbon material for graphite
24:14
that could better intercalate lithium-ions between its layers.
24:18
And in 1991, Sony launched the first commercial lithium-ion battery inside this,
24:23
the Sony Handycam.
24:25
Their battery was compact, rechargeable, powerful, and crucially, free of unstable lithium metal.
24:32
It was Sony who first coined the name lithium-ion and it stuck.
24:38
But this wasn't just about one camcorder.
24:41
Competing companies like Panasonic and Sanyo raced to catch up.
24:45
Lithium-ion batteries started appearing in phones, CD players, laptops.
24:49
Manufacturers actually began to advertise the use of lithium-ion batteries
24:53
as a key selling point of their products. - I'm showing my age here.
24:56
I joined the industry when lithium-ion cells were first introduced,
25:00
and there was a Sony camcorder that was introduced,
25:03
and then there was Dell computer.
25:04
And I still remember the ads when Dell computer introduced their lithium-ion battery,
25:08
and they had eight hours of runtime,
25:10
so they had an advertisement in a magazine and it was eight pages long.
25:14
Each one was an hour longer,
25:15
so it was a big deal. -
25:17
But what's crazy is
25:18
that even after all this,
25:19
these batteries should never have worked.
25:21
See, when you charge the battery for the first time,
25:24
lithium-ions move from the cathode to the graphite anode.
25:27
And here, they react with the electrolyte to form this weird complex patchwork of
25:32
compounds that build up on the anode's surface.
25:36
These parasitic side reactions should keep going on indefinitely,
25:39
using up all the lithium and destroying the cell but they don't.
25:44
Instead they form a thin protective layer known as the solid electrolyte interface,
25:49
or SEI.
25:50
It's a kind of chemical shield protecting both the graphite anode
25:53
and the electrolyte from further reactions.
25:56
But crucially, lithium-ions can still slip through it.
26:00
When the SEI originally forms during the first charging cycle,
26:04
around 5% of the lithium in the cell actually gets stuck in this layer,
26:08
decreasing the battery's capacity.
26:10
But this little trade off is what makes the battery stable enough to be
26:13
used for years or even decades,
26:16
which is why today lithium-ion batteries are virtually everywhere.
26:20
From 1991 to 2023,
26:22
the price per kilowatt hour dropped by 99% from nearly $9,000 to just $100.
26:29
At the same time, energy density and cycle life,
26:32
how many times a battery can be charged and discharged before it wears out,
26:36
improved dramatically, crossing a critical threshold.
26:39
Lithium-ion batteries had become powerful enough and finally cheap enough for something bigger,
26:44
the return of the electric car.
26:48
Today, lithium-ion powers a $100 billion industry.
26:52
In 2019, Whittingham, Goodenough
26:54
and Yoshino finally received the Nobel Prize in chemistry for an invention
26:58
that in the committee's words "Revolutionized our way of life."
27:02
This made Goodenough the oldest Nobel laureate in history,
27:06
receiving the award at the age of 97.
27:10
But lithium-ion isn't perfect. - Scary moments aboard a JetBlue plane,
27:15
a fire erupting after a passenger's backpack suddenly exploded. - Every week, inside an airplane,
27:20
there is at least one event of a battery, of a phone,
27:24
of an iPad or a toy or something that catches fire. - What,
27:28
every week? - Yeah, every week. - It's just the latest incident aboard a
27:32
plane involving lithium-ion batteries. -
27:35
So far this year,
27:36
60 onboard battery incidents through early October. - Every flight in the US has
27:42
a bag,
27:43
a specialized bag with very thick non-flammable materials where you put the phone inside,
27:49
and you close it,
27:50
and you still have a hazard and you have to deal with these gases,
27:53
but now you have put the fire ignition away from anything else.
27:58
And if it burst into fireworks, then at least it's in a container.
28:02
And then you tell the captain,
28:03
"We need to land immediately." -
28:06
So what is actually happening
28:07
when a battery fails like
28:08
that? - This is a classic lithium-ion battery,
28:12
and today we're gonna do something I always wanted to do.
28:14
We're gonna tear one down.
28:16
I guess safe to say don't do this at home.
28:19
But what would happen
28:20
if you were to do this outside of the gloved box? -
28:22
If you charged up the cell
28:24
and then you tried to tear it up,
28:26
then you could accidentally short it,
28:28
and then it could burn and it could even explode or fire.
28:32
If you discharged it and you opened it up,
28:34
you'd release all the different gases and really toxic chemicals,
28:39
and if you inhale those, then you'd probably end up in hospitals.
28:44
So at this point, we have what we call the jelly roll.
28:47
So that's a roll off the cathode,
28:48
separates that anode. - Yeah. - Stuck together with bit of tape.
28:52
So Li Ren's just gonna scalpel off the tape,
28:54
and then we should be able to unroll it into a nice sheet. -
28:58
So these little patches are the electrolyte
28:59
or? - Yeah. - Okay. -
29:00
So as time goes by,
29:01
it'll start evaporating out. - That is so cool.
29:05
It's so obvious when you see it,
29:06
but I don't think anyone intuitively thinks
29:09
that it's a rolled up like sheet of anode
29:11
and cathode inside.
29:13
But these layers inside the battery, they're not gonna stay perfect forever.
29:17
Here's an electrode from a new cell compared to one from an old one.
29:21
You can see that the lithium is building up in all of the wrong
29:24
places,
29:24
and if this sort of degradation gets out of hand, well,
29:28
we're about to push the cell past its breaking point.
29:32
How do we blow up a battery? - So today we've got a prismatic battery.
29:36
It's a small battery from sort of a power tool
29:39
or a phone or something similar.
29:41
We're gonna wrap it in some nichrome wire,
29:43
so we pass current through this wire.
29:45
Something like 200 watts we pass through- - That's a lot. - This wire.
29:49
Yeah, and it's a significant battery.
29:50
We want it to go
29:51
and we want it to go pretty spectacularly. (tense music) (scientists laughing) - Good
29:58
luck,
29:58
Harry.
29:59
What we're simulating here is a catastrophic battery failure,
30:02
the kind that could happen if a cell is damaged or overheated,
30:06
or even just badly manufactured.
30:08
It starts around 80 degrees Celsius
30:10
when the protective SEI layer on the anode starts to break down.
30:14
It's gonna try to reform, but these reactions are gonna release more heat,
30:19
and if that heat can escape, the temperature is gonna keep rising.
30:24
How close is it to exploding now?
30:26
What do you think? - It should burst very soon. - Seconds. - At
30:29
roughly 130 degrees Celsius,
30:31
the polymer separator is gonna melt,
30:33
and now the anode and cathode can come into direct contact,
30:37
and a massive internal short follows.
30:40
The cathode itself starts to decompose.
30:42
And because transition metal oxides release oxygen from their crystal structure,
30:47
they're gonna fuel the combustion, and now the fire is just feeding itself.
30:54
Oh. - Yes! - Oh, oh my God. (dramatic music) That's really violent.
30:59
This is insane, from one small battery like
31:01
that. - And it's only 50% state of charge. - What we call ignition
31:06
happens inside the battery,
31:07
not outside the battery,
31:08
and it requires a fuel or a substance that will undergo a reaction,
31:14
it requires an oxidizer or the equivalent oxidizer and it requires heat.
31:18
The battery contains these three inside,
31:21
so it has its own equivalent to an oxidizer,
31:24
its own equivalent to a fuel
31:25
and its own source of heat. - Yeah. - All of it in one
31:28
device. - So it's not actually lithium
31:32
that burns.
31:32
A modern lithium-ion battery like this one here contains very little lithium, ironically.
31:38
It's actually everything else inside here that's dangerous.
31:42
It must be really hard putting out a battery fire
31:45
if it really has everything
31:46
that it needs. - Yeah,
31:47
exactly.
31:48
So you can still put the blanket and stop the oxygen from arriving,
31:52
but you will not, the fire will not go to zero.
31:54
It will still, it will be smaller, but it will still be there.
31:57
And then with water, yeah, water has the ability to take heat away,
32:00
so it is possible to take the heat away from the battery with water.
32:03
The best thing is to put
32:04
and immerse the battery into a bath of water. - Yeah. - It's brutal.
32:10
You can do it with one battery, with 10 batteries, with 15 batteries,
32:13
but when you have very large packs of batteries with thousands of batteries,
32:17
you cannot physically put that under water. - Yeah,
32:20
one thing that is popping up recently
32:22
as a threat to cities is electric car fires. - Well,
32:26
we know a lot of water works. - Yeah, well,
32:28
if there's a water source nearby, I guess, yeah. - Yeah, I mean,
32:31
this is what they do in some countries around the world.
32:34
They have a truck, a specialist truck full of water,
32:37
and you just take the car
32:38
that has been involved in electric fire
32:40
and they dump it into it. - No way. - Yeah,
32:42
they do.
32:43
But, and actually it works. - So, how dangerous is it really? - It's very rare.
32:49
Every million batteries, there is a fire. - Okay. - Right.
32:51
So that's very safe, that in the standards of engineering, that's like, oh,
32:54
you have a good system.
32:55
One out of a million, that's fine.
32:57
But batteries are everywhere.
32:59
We don't even think about it.
33:01
So within our lifetimes,
33:03
we are going to reach a point where we would have been exposed to
33:06
more than a million batteries,
33:08
so we would be all of us experiencing a fire of a battery. -
33:11
With billions of batteries in circulation,
33:13
even rare failures become inevitable.
33:17
Meanwhile, demand is skyrocketing.
33:20
By 2030, we're projected to need over 17 million tons of battery grade materials,
33:25
and making lithium-ion batteries comes at a cost.
33:28
Lithium only makes up around 20 parts per million of Earth's crust.
33:32
It's expensive and water intensive to extract, and 70% of cobalt,
33:37
another key ingredient in many lithium-ion designs comes from the Democratic Republic of Congo,
33:42
much of it mined under hazardous, often exploitative conditions.
33:45
We need more batteries and we need them fast.
33:48
We can't just rely on lithium alone. -
33:51
So it's not like lithium's
33:52
as good as we're gonna get.
33:53
Like that we're gonna get much better batteries in the future.
33:56
If our priorities are about saving the planet from runaway climate change,
34:01
we need to have massive scale energy storage system
34:04
and electrify almost everything else
34:05
that we do. - The hunt is still on for safer batteries,
34:10
for cheaper ones, ones that last longer, charge faster,
34:13
and ones that store far more energy.
34:16
The lithium-ion battery changed the world,
34:18
but the future of energy storage won't be about just conquering one element,
34:23
it'll be about mastering many. (whooshing)
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